<ListView>
     <ListView.View>
          <GridView>
               <GridView.ColumnHeaderContainerStyle>
                    <Style TargetType="{x:Type GridViewColumnHeader}">
                        <Setter Property="Background" Value="LightBlue" />
                        <Setter Property="Foreground" Value="Black" />
                        <Setter Property="FontWeight" Value="Bold" />
                     </Style>
               </GridView.ColumnHeaderContainerStyle>

               <GridViewColumn Header="A?" Width="25"/>
               <GridViewColumn Header="#" Width="40"/>
               <GridViewColumn Header="Name" Width="120"/>
               <GridViewColumn Header="PTS" Width="30"/>
               <GridViewColumn Header="F" Width="30"/>
               <GridViewColumn Header="R" Width="30"/>
          </GridView>
     </ListView.View>
</ListView>