class User {
    @OneToMany(mappedBy = "user")
    private Set<UserService> userServices = new HashSet<UserService>();
}

class UserService {
    @ManyToOne
    @JoinColumn(name = "user_id")
    private User user;

    @ManyToOne
    @JoinColumn(name = "service_code")
    private Service service;

    @Column(name = "blocked")
    private boolean blocked;
}

class Service {
    @OneToMany(mappedBy = "service")
    private Set<UserService> userServices = new HashSet<UserService>();