static constexpr MyStruct ops[6] = {
    {'+', [&] (double a, double b) { return a+b; } },
    {'-', [&] (double a, double b) { return a-b; } },
    ...
};

typedef double (*binOp)(double, double);
struct MyStruct {
    char c;
    binOp fn;
};

std::function <double(double,double)> fn;

static const MyStruct ops[6] = {
    {'+', [] (double a, double b) { return a+b; } },
    {'-', [] (double a, double b) { return a-b; } },
};