<div class="container">
  <div class="row justify-content-center align-items-center">
    <form>
      <div class="form-group">
        <label for="formGroupExampleInput">Example label</label>
        <input type="text" class="form-control" id="formGroupExampleInput" placeholder="Example input">
      </div>
      <div class="form-group">
        <label for="formGroupExampleInput2">Another label</label>
        <input type="text" class="form-control" id="formGroupExampleInput2" placeholder="Another input">
      </div>
    </form>
  </div>
</div>

<div class="container h-100">
  <div class="row h-100 justify-content-center align-items-center">
    <form class="col-12">
      <div class="form-group">
        <label for="formGroupExampleInput">Example label</label>
        <input type="text" class="form-control" id="formGroupExampleInput" placeholder="Example input">
      </div>
      <div class="form-group">
        <label for="formGroupExampleInput2">Another label</label>
        <input type="text" class="form-control" id="formGroupExampleInput2" placeholder="Another input">
      </div>
    </form>
  </div>
</div>

html, body {
  height: 100%;
}
.container, .row.justify-content-center.align-items-center {
  height: 100%;
  min-height: 100%;
}

<section class="h-100">
  <header class="container h-100">
    <div class="d-flex align-items-center justify-content-center h-100">
      <div class="d-flex flex-column">
        <h1 class="text align-self-center p-2">item 1</h1>
        <h4 class="text align-self-center p-2">item 2</h4>
        <button class="btn btn-danger align-self-center p-2" type="button" name="button">item 3</button>
      </div>
    </div>
  </header>
</section>