Why can't I .add a Dictionary(Key, Value) in a foreach?

Dictionary<string, string> persons = new Dictionary<string, string>();

persons.Add("roger", "12");
persons.Add("mary", "13");

foreach (KeyValuePair<string,string> person in persons)
{
 Console.WriteLine("Name: " + person.Key + ", Age: " + person.Value);
 persons.Add("Xico", "22");
}