class MyComponent extends React.Component {
  constructor(props) {
    super(props)
    if (props.invalid) {
      throw new Error('invalid')
    }
  }
}

const wrapper = shallow(
  <MyComponent invalid />
)

it('should throw', () => {
  function fn() {
    if (wrapper.instance().props.invalid) {
      throw new Error('invalid')
    }
  }
  expect(fn).toThrow()
})