App-V 5 DynamicConfig

    <UserScripts>
      <StartVirtualEnvironment>
        <Path>POWERSHELL.EXE</Path>
        <Arguments>-ExecutionPolicy ByPass -ExecutionPolicy ByPass -command "New-Item -path Registry::'HKCU\SOFTWARE\Microsoft\Windows NT\CurrentVersion\AppCompatFlags\Layers' -Force;New-ItemProperty Registry::'HKCU\SOFTWARE\Microsoft\Windows NT\CurrentVersion\AppCompatFlags\Layers' -Name '[{Local AppData}]\Microsoft\AppV\Client\Integration\798F4668-A3EF-4849-A9D8-1933241DC39C\Root\Adobe Photoshop CS5\Photoshop.exe' -Value RUNASADMIN -PropertyType 'String'"</Arguments>
        <Wait RollbackOnError="false" />
      </StartVirtualEnvironment>


Usage: http://ittechlog.wordpress.com/2013/10/11/virtualize-adobe-photoshop-cs5-using-microsoft-app-v-5-0/