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- Static and Dynamic Equilibrium
- Inquiry question: What happens when chemical reactions do not go through to completion?
- Students:
- ● conduct practical investigations to analyse the reversibility of chemical reactions, for example:
- – cobalt(II) chloride hydrated and dehydrated
- – iron(III) nitrate and potassium thiocyanate
- – burning magnesium
- – burning steel wool (ACSCH090)
- ● model static and dynamic equilibrium and analyse the differences between open and closed systems (ACSCH079, ACSCH091)
- ● analyse examples of non-equilibrium systems in terms of the effect of entropy and enthalpy, for example:
- – combustion reactions
- – photosynthesis
- ● investigate the relationship between collision theory and reaction rate in order to analyse chemical equilibrium reactions Factors that Affect Equilibrium
- Inquiry question: What factors affect equilibrium and how?
- Students:
- ● investigate the effects of temperature, concentration, volume and/or pressure on a system at equilibrium and explain how Le Chatelier’s principle can be used to predict such effects, for example:
- – heating cobalt(II) chloride hydrate
- – interaction between nitrogen dioxide and dinitrogen tetroxide
- – iron(III) thiocyanate and varying concentration of ions (ACSCH095)
- ● explain the overall observations about equilibrium in terms of the collision theory (ACSCH094)
- ● examine how activation energy and heat of reaction affect the position of equilibrium
- Calculating the Equilibrium Constant (Keq)
- Inquiry question: How can the position of equilibrium be described and what does the equilibrium constant represent?
- Students:
- ● deduce the equilibrium expression (in terms of Keq) for homogeneous reactions occurring in solution
- ● perform calculations to find the value of Keq and concentrations of substances within an equilibrium system, and use these values to make predictions on the direction in which a reaction may proceed
- ● qualitatively analyse the effect of temperature on the value of Keq (ACSCH093)
- ● conduct an investigation to determine Keq of a chemical equilibrium system, for example:
- – Keq of the iron(III) thiocyanate equilibrium (ACSCH096)
- ● explore the use of Keq for different types of chemical reactions, including but not limited to:
- – dissociation of ionic solutions
- – dissociation of acids and bases (ACSCH098, ACSCH099)
- Solution Equilibria
- Inquiry question: How does solubility relate to chemical equilibrium?
- Students:
- ● describe and analyse the processes involved in the dissolution of ionic compounds in water
- ● investigate the use of solubility equilibria by Aboriginal and Torres Strait Islander Peoples when removing toxicity from foods, for example:
- – toxins in cycad fruit
- ● conduct an investigation to determine solubility rules, and predict and analyse the composition of substances when two ionic solutions are mixed, for example:
- – potassium chloride and silver nitrate (KCl + AgNO3 -> KNO3 + AgCl)
- – potassium iodide and lead nitrate
- – sodium sulfate and barium nitrate
- ● derive equilibrium expressions for saturated solutions in terms of Ksp and calculate the solubility of an ionic substance from its Ksp value
- ● predict the formation of a precipitate given the standard reference values for Ksp
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