<receiver android:name=".NewOutgoingCallReceiver">
   <intent-filter>
<action android:name="android.intent.action.NEW_OUTGOING_CALL" />
   </intent-filter>
  </receiver>

public class NewOutgoingCallReceiver extends BroadcastReceiver
{

@Override
public void onReceive( Context context, Intent intent )
  {
     // here i want to check which sim is making that new call
  }
}