mygeo=# CREATE TABLE uso_ocupacao_ibitinga_2 AS
SELECT
       gid,
       (gv).val,
       (gv).geom
 FROM (
       SELECT
              gid,
              ST_Intersection(rast, geom) AS gv
       FROM
            municipios,
            uso_ocupacao_solo
       WHERE
             ST_Intersects(rast, geom)
       AND   nome = 'Araraquara'
      )
AS tmp;

ERROR:  GEOSIntersects: TopologyException: side location conflict at -48.265729627714023 -21.544296308489137
CONTEXT:  PL/pgSQL function _st_intersects(geometry,raster,integer) line 22 at RETURN
PL/pgSQL function st_intersection(geometry,raster,integer) line 5 at assignment
SQL function "st_intersection" statement 1