XML
<Setting>
    <Datacopy Dir="C:\Datacopy">
    <Row Source="M:\Down" Destination="Downloads" Subfolder="" />
    <Row Source="P:\Temp" Destination="Temp" Subfolder="" />
    <Row Source="P:\Music" Destination="Muziek" Subfolder="Muziek" />
    </Datacopy>
</Setting>

XAML
<Window
    xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
    xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
    xmlns:mc="http://schemas.openxmlformats.org/markup-compatibility/2006"
    Title="Datacopy" Height="438" Width="597" ResizeMode="NoResize" WindowStartupLocation="CenterScreen">
    <Grid>
        <DataGrid x:Name="DatacopyGrid" AutoGenerateColumns="False" HorizontalAlignment="Left" Margin="10,10,0,0" VerticalAlignment="Top" Height="357" Width="639">
            <DataGrid.Columns>
                <DataGridTextColumn Binding="{Binding [0]}" Header="Bron map" Width="380" />
                <DataGridTextColumn Binding="{Binding [1]}" Header="Doel library" Width="250" />
            </DataGrid.Columns>
        </DataGrid>
        <Button x:Name="DatacopyBtnStart" Content="Start" HorizontalAlignment="Left" Margin="10,373,0,0" VerticalAlignment="Top" Width="75"/>
    </Grid>
</Window>