Loading config from C:\Sickbeard\SickBeard-win32-alpha-build496\autoProcessTV\autoProcessTV.cfg
Opening URL: http://localhost:8081/home/postprocess/processEpisode?nzbName=Show.HDTV.x264-FQM.nzb&quiet=1&dir=C%3A%5CSDownload%5Ccomplete%5CShow.HDTV.x264-FQM
Processing folder C:\Download\complete\Show.HDTV.x264-FQM

You're trying to post process an episode that's already been moved to its show dir