['United States'] 328,131,075

allowed_domains = ["geoba.se/country.php?cc=DE"]
start_urls = ['http://geoba.se/country.php?cc=DE/']

def parse(self, response):

    country = response.xpath('//*[@id="wrap"]/div[2]/div[2]/div[1]/div[1]/h2/b/text()').extract()
    pop_total = response.xpath('//td/div/table/tr/td[2]/text()').extract_first()

    print(country, pop_total)

['Germany'] 80,594,017