NSMutableDictionary *clipDetails = [NSMutableDictionary dictionary];
[clipDetails setObject:[NSNumber numberWithInteger:currentStream] forKey:@"stream"];
[clipDetails setObject:startTime forKey:@"clipStart"];
[clipDetails setObject:duration forKey:@"duration"];

CMTime startTime = (...);
NSValue *startValue = [NSValue valueWithBytes:&startTime objCType:@encode(CMTime)];
[clipDetails setObject:startValue forKey:@"startTime"];

CMTime startTime;
NSValue *startValue = [clipDetails objectForKey:@"startTime"];
[startValue getValue:&startTime];

clipDetails[@"startTime"] = ...;

NSValue *value = clipDetails[@"startTime"];

// Without ARC
 CFDictionaryRef timeAsDictionary = CMTimeCopyAsDictionary(startTime, kCFAllocatorDefault);
[clipDetails setObject:(NSDictionary*)timeAsDictionary forKey:@"clipStart"];
CFRelease(timeAsDictionary);