library(caret)

d<-twoClassSim(10000, intercept = -10, linearVars = 10, noiseVars = 10 )
c<-trainControl(method="cv",summaryFunction=twoClassSummary,classProbs=T,allowParallel = F)
train(Class~.,data=d, method="rpart", trControl=tc, tuneGrid = expand.grid(cp=c(2^-seq(1:24),0)), metric="ROC")

CART

10000 samples
   25 predictor
   2 classes: 'Class1', 'Class2'

No pre-processing
Resampling: Cross-Validated (10 fold)
Summary of sample sizes: 9001, 9001, 9000, 9000, 9000, 9000, ...
Resampling results across tuning parameters:

cp            ROC        Sens       Spec
0.000000e+00  0.8720221  0.9175038  0.6351468
5.960464e-08  0.8693352  0.9178879  0.6338036
1.192093e-07  0.8693352  0.9178879  0.6338036
2.384186e-07  0.8693352  0.9178879  0.6338036
4.768372e-07  0.8693352  0.9178879  0.6338036
9.536743e-07  0.8693352  0.9178879  0.6338036
1.907349e-06  0.8693352  0.9178879  0.6338036
3.814697e-06  0.8693352  0.9178879  0.6338036
7.629395e-06  0.8693352  0.9178879  0.6338036
1.525879e-05  0.8693352  0.9178879  0.6338036
3.051758e-05  0.8693352  0.9178879  0.6338036
6.103516e-05  0.8693352  0.9178879  0.6338036
1.220703e-04  0.8688977  0.9184034  0.6338036
2.441406e-04  0.8695238  0.9190479  0.6333571
4.882812e-04  0.8683167  0.9199503  0.6346964
9.765625e-04  0.8642201  0.9234327  0.6275635
1.953125e-03  0.8502711  0.9358066  0.6061528
3.906250e-03  0.8170988  0.9421235  0.5776111
7.812500e-03  0.7992001  0.9391563  0.5624742
1.562500e-02  0.7309271  0.9416099  0.4928790
3.125000e-02  0.7279783  0.9249799  0.5267897
6.250000e-02  0.7279783  0.9249799  0.5267897
1.250000e-01  0.6607248  0.9497346  0.3688948
2.500000e-01  0.5000000  1.0000000  0.0000000
5.000000e-01  0.5000000  1.0000000  0.0000000

ROC was used to select the optimal model using  the largest value.
The final value used for the model was cp = 0.0002441406.