# vi /etc/postfix/aliases

abuse: noc@isp.com, bob@isp.com, techgroup@isp.com, postmaster

root: tom

root: tom@example.com

# newaliases

# tail -f /var/log/mailog

Jan  8 03:56:33 www330 postfix[13209]: p089uXvh013209: from=root, size=29, class=0, nrcpts=1, msgid=<201101080956.p089uXvh013209@www330.nixcraft.net.in>, relay=root@localhost
Jan  8 03:56:33 www330 postfix[13210]: p089uXZH013210: from=, size=337, class=0, nrcpts=1, msgid=<201101080956.p089uXvh013209@www330.nixcraft.net.in>, proto=ESMTP, daemon=MTA, relay=localhost.localdomain [127.0.0.1]
Jan  8 03:56:33 www330 postfix[13209]: p089uXvh013209: to=root, ctladdr=root (0/0), delay=00:00:00, xdelay=00:00:00, mailer=relay, pri=30029, relay=[127.0.0.1] [127.0.0.1], dsn=2.0.0, stat=Sent (p089uXZH013210 Message accepted for delivery)
Jan  8 03:56:34 www330 postfix[13211]: STARTTLS=client, relay=cyberciti.biz.s9a1.psmtp.com., version=TLSv1/SSLv3, verify=FAIL, cipher=AES256-SHA, bits=256/256
Jan  8 03:56:36 www330 postfix[13211]: p089uXZH013210: to=vivek@nixcraft.net, ctladdr= (0/0), delay=00:00:03, xdelay=00:00:03, mailer=esmtp, pri=30576, relay=cyberciti.biz.s9a1.psmtp.com. [202.xxx.yyy.zzz], dsn=2.0.0, stat=Sent (Thanks)