import numpy as np
...
shape = np.shape((6, 6)) #This will be some pre-determined size
sigma = np.diag(S) #diagonalise the matrix - this works
my_sigma = sigma.resize(shape) #Resize the matrix and fill with zeros - returns "None" - why?

[x x x]

[x 0 0]
[0 x 0]
[0 0 x]
[0 0 0]
[0 0 0]
[0 0 0] - or some similar size, but the diagonal elements are important.

import numpy as np
...
shape = (6, 6) #This will be some pre-determined size
sigma = np.diag(S) #diagonalise the matrix - this works
sigma.resize(shape) #Resize the matrix and fill with zeros

# This assumes that you have a 2-dimensional array
zeros = np.zeros(shape, dtype=np.int32)
zeros[:sigma.shape[0], :sigma.shape[1]] = sigma

import numpy as np

A = np.array([1, 2, 3])

N = A.size
B = np.pad(np.diag(A), ((0,N),(0,0)), mode='constant')

[[1 0 0]
 [0 2 0]
 [0 0 3]
 [0 0 0]
 [0 0 0]
 [0 0 0]]

bigger_sigma = np.zeros(shape, dtype=sigma.dtype)
diag_ij = np.diag_indices_from(sigma)
bigger_sigma[diag_ij] = sigma[diag_ij]

a = [1, 2, 3]
b = []
for i in range(6):
    b.append((([0] * i) + a[i:i+1] + ([0] * (len(a) - 1 - i)))[:len(a)])

[[1, 0, 0], [0, 2, 0], [0, 0, 3], [0, 0, 0], [0, 0, 0], [0, 0, 0]]

S= np.ones((3))
print (S)
# [ 1.  1.  1.]
d= np.diag(S)
print(d)
"""
[[ 1.  0.  0.]
 [ 0.  1.  0.]
 [ 0.  0.  1.]]

"""

np.resize(d,(6,3))
"""
adds a repeating value
array([[ 1.,  0.,  0.],
       [ 0.,  1.,  0.],
       [ 0.,  0.,  1.],
       [ 1.,  0.,  0.],
       [ 0.,  1.,  0.],
       [ 0.,  0.,  1.]])
"""

d.resize((6,3),refcheck=False)
print(d)
"""
[[ 1.  0.  0.]
 [ 0.  1.  0.]
 [ 0.  0.  1.]
 [ 0.  0.  0.]
 [ 0.  0.  0.]
 [ 0.  0.  0.]]
"""