String url = "http://yourserver.com/upload.php";
File file = new File("myfileuri");
try {
    HttpClient httpclient = new DefaultHttpClient();

    HttpPost httppost = new HttpPost(url);

    InputStreamEntity reqEntity = new InputStreamEntity(new FileInputStream(file), -1);
    reqEntity.setContentType("binary/octet-stream");
    reqEntity.setChunked(true); // Send in multiple parts if needed
    httppost.setEntity(reqEntity);
    HttpResponse response = httpclient.execute(httppost);
    //Do something with response...

} catch (Exception e) {
    e.printStackTrace();
}

httppost.setEntity(new UrlEncodedFormEntity(nameValuePairs));

File myFile = new File("/path/to/file.png");
    RequestParams params = new RequestParams();
    try {
        params.put("profile_picture", myFile);
    } catch(FileNotFoundException e) {}